全文获取类型
收费全文 | 1618篇 |
免费 | 84篇 |
国内免费 | 10篇 |
专业分类
化学 | 956篇 |
晶体学 | 5篇 |
力学 | 84篇 |
综合类 | 1篇 |
数学 | 372篇 |
物理学 | 294篇 |
出版年
2023年 | 8篇 |
2022年 | 6篇 |
2021年 | 19篇 |
2020年 | 24篇 |
2019年 | 24篇 |
2018年 | 28篇 |
2017年 | 21篇 |
2016年 | 56篇 |
2015年 | 54篇 |
2014年 | 51篇 |
2013年 | 100篇 |
2012年 | 98篇 |
2011年 | 112篇 |
2010年 | 78篇 |
2009年 | 77篇 |
2008年 | 93篇 |
2007年 | 108篇 |
2006年 | 94篇 |
2005年 | 89篇 |
2004年 | 86篇 |
2003年 | 81篇 |
2002年 | 49篇 |
2001年 | 20篇 |
2000年 | 16篇 |
1999年 | 20篇 |
1998年 | 14篇 |
1997年 | 19篇 |
1996年 | 20篇 |
1995年 | 14篇 |
1994年 | 21篇 |
1993年 | 18篇 |
1992年 | 14篇 |
1991年 | 12篇 |
1990年 | 16篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1985年 | 12篇 |
1984年 | 12篇 |
1983年 | 9篇 |
1982年 | 16篇 |
1981年 | 12篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1977年 | 12篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1974年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有1712条查询结果,搜索用时 15 毫秒
41.
Sabine Beernaerts Marie Gerard Philippe Debongnie Jean-Paul Barthelemy Luc Pussemier Alfred Copin 《International journal of environmental analytical chemistry》2013,93(6):469-480
A monitoring study was carried out in 1998-1999 on a medium-sized (c. 4580 km2) watershed of the Dyle (or Dijle) river in central Belgium, composed of both rural and urbanized areas. This watershed may be considered as representative of a large part of the country. Samples were taken each month from seven sites along the course of the river, plus one from its major affluent the Demer. The eight molecules monitored were the main herbicides used on the major crops in the area, plus some used in nonagricultural sectors. The concentrations found were mostly in the 0-3 μg/L range, with some peaks between 3 and 14 μg/L. The averages over all spring and summer samples analyzed ranged from 0.14 (bentazone) to 1.54 μg/L (diuron). Time and space specific patterns could be observed. 相似文献
42.
43.
Radu Ignat Luc Nguyen Valeriy Slastikov Arghir Zarnescu 《Comptes Rendus Mathematique》2013,351(13-14):533-537
We analyze the radially symmetric solution corresponding to the vortex defect (the so-called melting hedgehog) in the Landau–de Gennes theory for nematic liquid crystals. We prove the existence, uniqueness and stability results of the melting hedgehog. 相似文献
44.
45.
Luc Bélair 《代数通讯》2013,41(8):3785-3793
We use model-theoretic methods to give examples of pseudovaluation domains with Vapnik-Chervonenkis classes of definable sets. 相似文献
46.
Thermo‐ and pH‐sensitive triblock copolymers with tunable hydrophilic/hydrophobic properties 下载免费PDF全文
Christophe Pottier Gaëlle Morandi Virginie Dulong Zied Souguir Luc Picton Didier Le Cerf 《Journal of polymer science. Part A, Polymer chemistry》2015,53(22):2606-2616
Polymers consisting of poly(acrylic acid) (PAA) and statistical poly[(acrylic acid)‐co‐(tert‐butylacrylate)] (P(AA‐co‐tBA)), attached to both extremities of Jeffamine® (D series based on a poly(propylene oxide) (PPO) with one amine function at each end) using atom transfer radical polymerization (ATRP) are presented in this article. An original bifunctional amide‐based macroinitiator was first elaborated from Jeffamine®. tBA polymerization was subsequently initiated from this macroinitiator. This polymerization occurs in a well‐controlled manner leading to narrow molecular weights distribution. Amphiphilic copolymers were finally obtained after complete or partial hydrolysis of the PtBA blocks into PAA. The control of the partial hydrolysis of tBA units, conducted in a concentrated HCl/tetrahydrofuran mixture, is demonstrated. The properties of the triblock copolymers were preliminary investigated in aqueous solution by absorbance, DLS measurements and SEC/MALS/DV/DRI analysis as a function of temperature and pH modifications, providing evidences of thermo‐ and pH‐sensitive self‐assembly of the copolymers. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2606–2616 相似文献
47.
Charlotte Duval Cécile Nouvel Jean‐Luc Six 《Journal of polymer science. Part A, Polymer chemistry》2014,52(8):1130-1138
Poly(d,l ‐lactide‐co‐glycolide) (PLGA) copolyesters are commonly used in biomedical applications. Researches were carried out on nontoxic or low‐toxic catalysts that are enough efficient to provide short polymerization times, adequate microstructure chains and similar properties than the commercial PLGA materials. In this study, PLGA were synthesized by ring‐opening copolymerization (ROP) using three different catalysts. Stannous octoate is the first catalyst we used, as it is very efficient, even its toxicity is still on debate. Two others low‐toxic catalysts [zinc lactate and bismuth subsalicylate (BiSS)] were also evaluated. The comparison of these ROP was realized in terms of kinetics and control of the polymerization. Then, the influence of the catalyst on the PLGA microstructure chains is reported. Finally, abiotic hydrolytic degradation rate is studied. Results described in this article show that BiSS is one very attractive catalyst to produce low toxic PLGA for biomedical applications. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1130–1138 相似文献
48.
Taratra André Fenoradosoa Céline Laroche Cedric Delattre Virginie Dulong Didier Le Cerf Luc Picton Philippe Michaud 《Applied biochemistry and biotechnology》2012,167(5):1303-1313
The rheological behavior of a sulfated galactan extracted from Halymenia durvillei, a red seaweed collected in the coastal waters of a small island of Madagascar (Nosy-be in Indian Ocean), was investigated in dilute and semi-dilute solutions. In dilute solution with NaCl at 0.3?M, the polysaccharide adopted a coil conformation whereas, at higher concentrations, the polymer had the behavior of shear-thinning fluid, typical of polymer with high molar mass or semi-rigid conformation. Degradations of this lambda carrageenan-like, using radical depolymerization, and high-pressure homogenization led to several samples of various and controlled molar masses. The measure of their intrinsic viscosities permitted the determination of the relationship of Mark?CHouwink?CSakurada. 相似文献
49.
Fabián Flores-Bazán Dinh The Luc Antoine Soubeyran 《Journal of Optimization Theory and Applications》2012,155(3):883-901
We study reference-dependent preference relations defined by a real-valued bivariate function and prove an existence criterion for maximal elements. Then we formulate a generalized version of the well-known Brondsted maximum principle and apply it to behavioral traps and Nash equilibrium in games with preference relations that are not necessarily partial orders. 相似文献
50.
Marián Masár Pavol Kruk Milan Luc Róbert Bodor Ladislav Danč Peter Troška 《Electrophoresis》2013,34(3):432-440
Adsorption processes on a PMMA chip linked with CZE separations of a group of 13 aliphatic and aromatic mono‐ and di‐amines were studied. Due to the lack of chromophores within aliphatic amines, contact conductivity detection implemented directly onto the chip was used for monitoring of cationic CZE separations. To prevent an adsorption of studied amines to the chip channels, the surface of PMMA chip was modified by dynamic coating. Different surface modifiers, such as aliphatic oligoamines (diethylenetriamine and triethylenetetramine), were added to the BGE solutions filling the chip channels. The effect of various concentrations of surface modifiers on peak profiles and separation parameters of amines was monitored. Of these, mainly, aliphatic di‐amines and aromatic mono‐amines adversely affected the CZE resolution of a whole group of analytes by their strong adsorption to the chip channels. A propionate BGE with pH 3.2 containing 100 μM triethylenetetramine and 25 mM 18‐crown‐6‐ether was found suitable for CZE resolution of 12 from a total of 13 amines studied. Simple dynamic modification of the surface of PMMA chip enabled fast (analysis time lasted 9 min), sensitive (sub‐μM LODs reached) and reproducible (1–3% RSD of the peak areas) CZE analysis of the aliphatic and aromatic amines. 相似文献